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中国公民于某,1990年与妻子离婚,所生两个子女由前妻抚养,1995年,于某到西班牙经商。2001年与一西班牙女子结婚,按照天主教仪式举行了婚礼,按照西班牙婚姻法规定,天主教徒到天主教堂举行结婚仪式为双方缔结婚姻的形式要件。2002年,于某结束在西班牙的生意,回北京投资办厂,并购有楼房一栋,另有一些古董及银行存款。2005年2月,于某在上海因车祸去世,未留遗嘱。关于遗产继承问题,于某与前妻所生的子女同他在西班牙的妻子之间发生争执,于的子女认为于某在西班牙结婚他们一无所知,于某的婚姻未进行民事登记,不符合我国婚姻法的规定,因此于某的西班牙妻子不是于某的继承人。
问:1.于某在西班牙的婚姻是否有效?请说明理由。
        2.本案应如何适用法律?说明理由。
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